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Kumar, Naveen
- Ability of Sugar based Glucoside Surfactants to Remove Petroleum Contaminants
Abstract Views :295 |
PDF Views:2
Authors
Affiliations
1 Department of Chemical Engineering, Jaypee Univesity of Engineering and Technology, Guna, Madhya Pradesh, IN
1 Department of Chemical Engineering, Jaypee Univesity of Engineering and Technology, Guna, Madhya Pradesh, IN
Source
Journal of Surface Science and Technology, Vol 31, No 3-4 (2015), Pagination: 156-163Abstract
A study is carried out to evaluate the efficiency of synthesized sugar based alkyl polyglucosides (APG10, APG12, APG14) for washing petroleum oil contaminants from soil in the shallow perched aquifers. Their efficiencies were compared with other commercially important non-ionic surfactants. viz. Tween-20, Tween-40 and Brij-58. The APG10 was synthesized from anhydrous glucose and decyl alcohol in the presence of an acid catalyst in a cost effective manner. The spectroscopic tools viz, FTIR, NMR, thin layer and mass chromatographic techniques were used for structural elucidation of APG10. Based on the measurement of critical micelle concentration, the preferred concentrations of aqueous surfactant solutions for soil washing are determined. The batch washing experiments have shown that the oil removal efficiencies decrease in the following order APG14>Brij-58>APG12 >APG10>Tween-40>Tween-20. Biodegradability test of the APG10 have been carried out by modified OECD (Organization for Economic Cooperation&Development) screening method to evaluate its environmental compatibility. More than 90% surfactants are found to degrade within one week period in river water.Keywords
Alkyl Polyglucosides, Petroleum Contaminants, Washing from Soil.
References
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- Mixed Micelle Properties of Anionic Dimeric Surfactants with Anionic, Cationic, and Nonionic Surfactants
Abstract Views :148 |
PDF Views:1
Authors
Naveen Kumar
1,
Rashmi Tyagi
2
Affiliations
1 Department of Chemistry, Shobhit University, Gangoh, Saharanpur - 247341, Uttar Pradesh, IN
2 Department of Chemistry, Jaypee University of Engineering & Technology, Guna - 473226, Madhya Pradesh, IN
1 Department of Chemistry, Shobhit University, Gangoh, Saharanpur - 247341, Uttar Pradesh, IN
2 Department of Chemistry, Jaypee University of Engineering & Technology, Guna - 473226, Madhya Pradesh, IN
Source
Journal of Surface Science and Technology, Vol 37, No 3-4 (2021), Pagination: 173-178Abstract
Herein, we have investigated the mixed micellar behavior of carboxylate anionic dimeric surfactants (CAD12 and CAD16) with commercial surfactants; anionic type i.e., sodium dodecyl sulfate, cationic i.e., cetyltrimethylammonium bromide and nonionic i.e., polyethylene glycol p-(1,1,3,3-tetramethylbutyl)-phenyl ether. The CMC values of mixed surfactants obtained from conductivity data decrease with a mole fraction of dimeric surfactants. The micellar characteristics (ideal CMC) and mutual interaction parameters (β) have been computed with the aid of theoretical models proposed by Clint, and Rubingh. In addition to this, thermodynamic parameters of micellization like ∆Gmic0, ∆Hmic0 , and ∆Smic0 were evaluated and discussed.Keywords
Conventional Surfactants, Critical Micelle Concentration, Dimeric Surfactants, Interaction Parameter, Mixed Micellization.References
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